Empirical Correlations For the Estimation of Free Energies of Fusion of Cubic Monoxides

Author

Mark E. Schlesinger, Missouri University of Science and TechnologyFollow

Abstract

The existing thermodynamic database for NaCl-cubic alkali halides has been used to derive empirical relationships that allow prediction of the free energy of fusion with respect to temperature of monoxides with a similar crystal structure. Compound melting points and ionicities play a role in the estimation technique, and a correction is made for the effect of high-temperature disordering in some compounds. ΔGf for MnO and NiO are estimated using the new technique, and are compared with previous efforts.

Recommended Citation

M. E. Schlesinger, "Empirical Correlations For the Estimation of Free Energies of Fusion of Cubic Monoxides," High Temperature Science, Humana Press, Jan 1990.

Department(s)

Materials Science and Engineering

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1990 Humana Press, All rights reserved.

Publication Date

01 Jan 1990