Adsorption of Dispersants on Zirconia Powder in Tape‐casting Slip Compositions

Editor(s)

Green, David J. and Halloran, John and Johnson, David W., Jr. and Klein, Lisa

Abstract

This paper reports the extension of the more fundamental work of Tormey et al. on the effectiveness of a common dispersant (menhaden fish oil) and a model system (glycerol trioleate) to tape-casting slip formulation. the adsorption isotherms of the two adsorbates on doped zirconia from methyl ethyl ketone—ethanol solutions were measured by thermogravimetric analysis of solutions equilibrated with the powder surface. Viscosity decreased while sintered density increased in tape-cast samples prepared to dispersant concentrations corresponding to points along the adsorption isotherm in a way which follows the isotherm if binder competition for surface sites is considered.

Department(s)

Materials Science and Engineering

Keywords and Phrases

Zirconia; Tape Casting; Adsorption; Dispersants

International Standard Serial Number (ISSN)

0002-7820; 1551-2916

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1989 Wiley-Blackwell, All rights reserved.

Publication Date

01 Jan 1989

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