Nitrogen Dissolution in Alkali-barium-metaphosphate Melts

Author

Mohan Rajaram
D. E. Day, Missouri University of Science and TechnologyFollow

Abstract

Phosphorus oxynitride glasses were prepared by remelting 30R2O-20BaO-50P2O5, (R=Li, Na or K) glasses in anhydrous ammonia. The nitrogen content of these metaphosphate melts decreased with increasing size of the alkali ion. The dissolution rate in water and thermal expansion coefficient of the base glasses increased with increasing alkali ion size. The dissolution rate of the oxynitride glasses was lower than that of the base glasses but was essentially independent of the alkali ion. The thermal expansion coefficient of the oxynitride glasses increased with increasing alkali size as observed in other glasses.

Recommended Citation

M. Rajaram and D. E. Day, "Nitrogen Dissolution in Alkali-barium-metaphosphate Melts," Journal of Materials Science, Springer Verlag, Feb 1989.

The definitive version is available at https://doi.org/10.1007/BF01107444

Department(s)

Materials Science and Engineering

Keywords and Phrases

Polymer Sciences; Industrial Chemistry/Chemical Engineering; Characterization and Evaluation Materials; Mechanics

International Standard Serial Number (ISSN)

0022-2461

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1989 Springer Verlag, All rights reserved.

Publication Date

01 Feb 1989