Masters Theses

Abstract

"Several compounds containing the complex tetrachlorocuprate(II) anion, CuCl₄=, and various alkyl or aryl cations were prepared. These include bis(methylammonium)tetrachlorocuprate(II), bis(isopropylammoniumtetrachlorocuprate(II), 1,3-propanediammoniumtetrachlorocuprate(II), bis(furfuryl-ammonium)tetrachlorocuprate(II), and a series of ethylene ammonium salts. Some unsuccessful and difficult preparations are described. Spectra were taken in acetone, 4-butyrolactone, and methanoleaf An explanation of the effects of various solvents on the absorption spectrum and structure of the complex ion is given"--Abstract, page ii.

Advisor(s)

McDonald, H. O. (Hector O.)

Committee Member(s)

Tappmeyer, Wilbur P.
James, William Joseph

Department(s)

Chemistry

Degree Name

M.S. in Chemistry

Publisher

University of Missouri at Rolla

Publication Date

1967

Pagination

v, 30 pags, 6 plates

Note about bibliography

Includes bibliographical references (pages 26-27).

Rights

© 1967 Paul Douglas Griffin, All rights reserved.

Document Type

Thesis - Open Access

File Type

text

Language

English

Library of Congress Subject Headings

Ammonium salts
Sample preparation (Chemistry)
Complex ions
Absorption spectra

Thesis Number

T 2055

Print OCLC #

5994178

Electronic OCLC #

944121348

Griffin_Paul_1967_1a.tif (27462 kB)
[(2E3A)(HCl)] (CuCl<sub>4</sub>) 200 – 340 millimicrons

Griffin_Paul_1967_1b.tif (27379 kB)
[(2E3A)(HCl)] (CuCl₄) 340 – 900 millimicrons

Griffin_Paul_1967_1c.tif (27333 kB)
[(2E3A)(HCl)] (CuCl₄) 900 – 2800 millimicrons

Griffin_Paul_1967_2a.tif (27533 kB)
(3E2A) (CuCl₄) 220 – 340 millimicrons

Griffin_Paul_1967_2b.tif (27374 kB)
(3E2A) (CuCl₄) 340 – 900 millimicrons

Griffin_Paul_1967_2c.tif (27097 kB)
(3E2A) (CuCl₄) 900 – 2800 millimicrons

Included in

Chemistry Commons

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