Preparation and spectra of some new alkyl ammonium salts of the tetrachlorocuprate (II) ion.

Author

Paul Douglas Griffin

Abstract

"Several compounds containing the complex tetrachlorocuprate(II) anion, CuCl₄⁼, and various alkyl or aryl cations were prepared. These include bis(methylammonium)tetrachlorocuprate(II), bis(isopropylammoniumtetrachlorocuprate(II), 1,3-propanediammoniumtetrachlorocuprate(II), bis(furfuryl-ammonium)tetrachlorocuprate(II), and a series of ethylene ammonium salts. Some unsuccessful and difficult preparations are described. Spectra were taken in acetone, 4-butyrolactone, and methanoleaf An explanation of the effects of various solvents on the absorption spectrum and structure of the complex ion is given"--Abstract, page ii.

Advisor(s)

McDonald, H. O. (Hector O.)

Committee Member(s)

Tappmeyer, Wilbur P.
James, William Joseph

Department(s)

Chemistry

Degree Name

M.S. in Chemistry

Publisher

University of Missouri at Rolla

Publication Date

1967

Pagination

v, 30 pags, 6 plates

Note about bibliography

Includes bibliographical references (pages 26-27).

Rights

© 1967 Paul Douglas Griffin, All rights reserved.

Document Type

Thesis - Open Access

File Type

text

Language

English

Subject Headings

Ammonium salts
Sample preparation (Chemistry)
Complex ions
Absorption spectra

Thesis Number

T 2055

Print OCLC #

5994178

Electronic OCLC #

944121348

Link to Catalog Record

http://merlin.lib.umsystem.edu/record=b1067835~S5

Recommended Citation

Griffin, Paul Douglas, "Preparation and spectra of some new alkyl ammonium salts of the tetrachlorocuprate (II) ion." (1967). Masters Theses. 3192.
https://scholarsmine.mst.edu/masters_theses/3192