Sonogashira coupling reactions in the synthesis of near infra-red emitters and of star systems for the study of charge propagation in dendrimers
Keywords and Phrases
Sonogashira; Suzuki/Miyaura; Phenanthroline; Near-IR
"Sonogashira coupling reactions have been used for the synthesis of three functional systems: arylethynyl-substituted 9,10-anthraquinones, Os(II) bis(2,2'-bipyridine) (3,8-diarylethynyl-1,10-phenanthroline) complexes and four star-shaped molecules incorporating the 4-benzoyl-N-alkylpyridinium cation."--Abstract, page iv.
Ph. D. in Chemistry
University of Missouri--Rolla
Journal article titles appearing in thesis/dissertation
- Synthesis and study of 2-, 2,6- and 2,7- mono- and di-arylethynyl substituted 9,10-anthraquinones. Large Stokes shifts tunable by aryl substitution and solvent polarity
- Synthesis and near IR photoluminescence of Os(II) BIS(2,2'-bipyridine) (3,8-diarylethynyl-1,10-phenanthroline) complexes, study of the anomalous behavior of the 3,8-dinitrophenylethynyl-substituted homologue
- Redox-active star molecules based on the 4-benzoylpyridinium cation - implications for faster charge propagation along branches vs. across the perimeter in dendrimers
- Coupling of 3,8-dibromo-1,10-phenanthroline with 3,5-diethynylheptyloxybenzene: a Suzuki/Miyaura versus a Sonogashira perspective
xii, 119 leaves
© 2004 Jinhua Yang, All rights reserved.
Dissertation - Citation
Library of Congress Subject Headings
Organic compounds -- Synthesis
Print OCLC #
Link to Catalog Record
Full-text not available: Request this publication directly from Missouri S&T Library or contact your local library.http://laurel.lso.missouri.edu/record=b5135717~S5
Yang, Jinhua, "Sonogashira coupling reactions in the synthesis of near infra-red emitters and of star systems for the study of charge propagation in dendrimers" (2004). Doctoral Dissertations. 1529.