Title

Solid State Dynamics of Fe3(CO)12 Revisited

Abstract

An analysis of the temperature dependence of the Mössbauer spectral hyperfine parameters of Fe3(CO)12, in conjunction with recently reported temperature-dependent X-ray structural results, indicates different temperature dependences for the recoil-free fractions of the two iron sites, completely supports the presence of Goldanskii-Karyagin asymmetry in the Mössbauer spectra of this compound, and eliminates the possibility of 60° rotational disorder for the iron sites, at least on the Mössbauer time scale.

Department(s)

Chemistry

International Standard Serial Number (ISSN)

201669

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1996 American Chemical Society (ACS), All rights reserved.

Share

 
COinS