Solid State Dynamics of Fe3(CO)12 Revisited
An analysis of the temperature dependence of the Mössbauer spectral hyperfine parameters of Fe3(CO)12, in conjunction with recently reported temperature-dependent X-ray structural results, indicates different temperature dependences for the recoil-free fractions of the two iron sites, completely supports the presence of Goldanskii-Karyagin asymmetry in the Mössbauer spectra of this compound, and eliminates the possibility of 60° rotational disorder for the iron sites, at least on the Mössbauer time scale.
F. Grandjean and G. J. Long, "Solid State Dynamics of Fe3(CO)12 Revisited," Inorganic Chemistry, vol. 35, no. 16, pp. 4532-4533, American Chemical Society (ACS), Jul 1996.
The definitive version is available at https://doi.org/10.1021/ic960248i
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