Title

Crystal Structures of 1,1′-di(2-propanone)-2,2′-biimidazole Dihydrazone and 2,6-diacetylpyridine Dihydrazone

Abstract

The nucleophilic addition reactions between 1,1′-di(2-propanone)-2,2′-biimidazole or 2,6-diacetylpyridine and hydrazine hydrate afford 1,1′-di(2-propanone)-2,2′-biimidazole dihydrazone (1) and 2,6-diacetylpyridine dihydrazone (2), respectively. Compound 1 crystallizes in the orthorhombic space group P212121, with a = 9.042(2), b = 9.731(3), c = 15.683(4)Å, V = 1379.9(6)Å3 and Z = 4. Compound 2 crystallizes in the orthorhombic space group Pnma, with a = 10.948(2), b = 19.742(6), c = 4.566(1)Å, V = 986.9(4)Å3 and Z = 8. A pseudo center of inversion is present at the midpoint of the C-C bond joining the imidazole rings of 1, whose substituents crystallize in a trans configuration. The imidazole rings are rotated 2.5(3)° about the C-C bond. In contrast to the essentially planar structure of 2, the hydrazone substituent groups of 1 are at angles of 89.9(1)° and 88.4(1)° with respect to the plane of the adjacent imidazole moiety.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1997 Springer Verlag, All rights reserved.


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