Epitaxial Electrodeposition of Fe₃O₄ on Single-crystal Au(111)
An epitaxial film of Fe₃O₄ was electrodeposited from aqueous solution onto single-crystal Au(111) at 90 °C. the process did not require thermal annealing to initiate crystallization. the epitaxial film had a (111) out-of-plane orientation and two types of in-plane orientation (parallel and antiparallel with respect to the substrate). the electrochemical deposition of Fe₃O₄ may be a promising way to prepare epitaxial ferromagnetic-semiconductor and ferromagnetic-antiferromagnetic sandwich structures and multilayers for spin-polarized devices.
M. P. Nikiforov et al., "Epitaxial Electrodeposition of Fe₃O₄ on Single-crystal Au(111)," Advanced Materials, Wiley-VCH Verlag, Jan 2000.
The definitive version is available at https://doi.org/10.1002/1521-4095(200009)12:18<1351
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