Resistance Switching in Electrodeposited Magnetite Superlattices
(Graph Presented) Defect-chemistry magnetite superlattices and compositional superlattices in the magnetite/zinc ferrite system are electrodeposited as epitaxial films onto single-crystal Au(111). The defect-chemistry superlattices have alternating nanolayers with different Fe(III)/Fe(II) ratios, whereas the compositional superlattices have alternating nanolayers with different Zn/Fe ratios. The electrochemical/chemical (EC) nature of the electrodeposition reaction is exploited to deposit the superlattices by pulsing the applied potential during deposition. The defect-chemistry superlattices show low-to-high and high-to-low resistance switching that may be applicable to the fabrication of resistive random access memory (RRAM). Copyright © 2010 Chemical Society.
J. A. Switzer et al., "Resistance Switching in Electrodeposited Magnetite Superlattices," Journal of the American Chemical Society, American Chemical Society (ACS), Jan 2010.
The definitive version is available at https://doi.org/10.1021/ja909295y
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