One-step Synthesis and Redox Properties of Dodecahydro-3a,9a-diazaperylene - the Most Easily Oxidized P-phenylenediamine

Author

Abdel-Monem M. Rawashdeh
Chariklia Sotiriou-Leventis, Missouri University of Science and TechnologyFollow
Xuerong Gao
Nicholas Leventis, Missouri University of Science and TechnologyFollow

Abstract

Dodecahydro-3a,9a-diazaperylene (DHDAP) was prepared in one step from p-phenylenediamine and 1-bromo-3-chloropropane, and its first redox potential is 292 mV more negative than the first redox potential of N,N,N ,N -tetramethyl-p-phenyl enediamine (TMPD), thus becoming the most easily oxidized p-phenylenediamine homologue.

Recommended Citation

A. M. Rawashdeh et al., "One-step Synthesis and Redox Properties of Dodecahydro-3a,9a-diazaperylene - the Most Easily Oxidized P-phenylenediamine," Chemical Communications, Royal Society of Chemistry, Jan 2001.

The definitive version is available at https://doi.org/10.1039/b104991g

Department(s)

Chemistry

International Standard Serial Number (ISSN)

1359-7345

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2001 Royal Society of Chemistry, All rights reserved.

Publication Date

01 Jan 2001