Title

β,β-dichlorovinyldiazonium or Dichloro(diazomethyl)carbenium Ion? Crystal Structure and Electron Density Distribution of β,β- Dichlorovinyldiazonium Hexachloroantimonate

Abstract

The crystal structure of β,β-dichlorovinyldiazonium hexachloroantimonate, 2·SbCl6, and the topological electron density analysis of 2 provide compelling evidence for the importance of chlorine-stabilized carbenium ion resonance forms for the stabilization of vinyldiazonium ions by β-substitution.

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0022-4936

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1993 Royal Society of Chemistry, All rights reserved.

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