Seleno- and Tellurocarbenium Ions
α-Chalcogeno substituted carbenium salts [(RX) 3C] + PF6 - (X = S, Se, Te; R = 2, 4, 6-/Pr 3C6H2) obtained from reaction of the copper complexes [(bipy)CuXR] with CBfy are stabilized to the same extent; but the electronic mechanism is very different.
H. Gratzmacher et al., "Seleno- and Tellurocarbenium Ions," Paediatric and Perinatal Drug Therapy, vol. 1, no. 2, pp. 287-290, Librapharm Ltd., Jan 1997.
Keywords and Phrases
Carbenium Ions; Tellurium; Selenium; Stability; Ab initio calculations; Structures
International Standard Serial Number (ISSN)
Article - Journal
© 1997 Librapharm Ltd., All rights reserved.