Title

Polymorphism and C=N-N=C Conformational Isomers of Azines: X-ray Crystal and Ab Initio Structures of Two Rotational Isomers of Methyl (para-Tolyl) Ketone Azine

Abstract

Conjugative effects are not significant for the conformation of diaryl-substituted azines such as 1 - whether within the azine unit or between the aryl substituents and the azine or imino units. This was the conclusion of studies of X-ray crystal structures and quantum chemical calculations.

Department(s)

Chemistry

Sponsor(s)

Petroleum Research Fund of the American Chemical Society
Research Board of the University of Missouri
National Science Foundation

Comments

This research was supported by the Petroleum Research Fund of the American Chemical Society, the Research Board of the University of Missouri, and the National Science Foundation, and is part of the projected Ph.D. dissertation of G. S. Chen.

International Standard Serial Number (ISSN)

0570-0833

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1994 Wiley-VCH Verlag, All rights reserved.

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