Title

A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for Its Rearrangement

Abstract

Copper(I) oxide reacts with selenol 2,4,6-Pri3C6H2-SeH in ethanol to give the hexanuclear copper(I) selenolate {Cu[Se(2,4,6-Pri3C6H2)]}6 of 6, the solid state structure of which consists of a disordered Cu6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0022-4936

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1995 Royal Society of Chemistry, All rights reserved.

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