Abstract

C7H5N2O2 +.Cl-H2O, Mr = 202.60, monoclinic, C2c, a = 25.62(3), b = 4.964(2), c = 14.900 (14)Å, β = 107.15 (4)°, V = 1811 (3)Å3, Z = 8, Dx = 1.486 g cm-3, λ(Mo ) = 0.71073 Å, µ = 3.9 cm-1, F(000) = 832, T = 298 K, R = 0.035 for 1275 observed reflections. The terminal N atom of the diazonium group is bent away from the carboxyl group. The N2 and the carboxyl group are on opposite sides of the best plane of the aromatic ring and, importantly, the carboxyl group is not fully conjugated with the aromatic ring but instead is rotated [12.3 (1)°] around the C-CO2 axis.

Department(s)

Chemistry

Keywords and Phrases

Carbon Dioxide; Aromatic Rings; Carboxyl Groups; Aromatic Compounds

International Standard Serial Number (ISSN)

0108-2701; 1600-5759

Document Type

Article - Journal

Document Version

Final Version

File Type

text

Language(s)

English

Rights

© 1993 International Union of Crystallography (IUCr), All rights reserved.

Included in

Chemistry Commons

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