Title

A Study of the Pressure Induced Irrevesible Conversion of Distorted Tetrahedrahedral Dichloro-trans-2-(2'-quinolyl)methylene-3-quinuclidinonenickel(II), [Ni(qnqn)Cl2], into Binuclear Square Pyramidal [Ni(qnqn)Cl2]2

Abstract

Low-frequency i.r. spectral evidence has been obtained which indicates that the violet distorted tetrahedral complex, Ni(qnqn)Cl2, is irreversibly converted under pressure into its yellow, binuclear, square pyramidal isomer, [Ni(qnqn)Cl2]2; we believe this to be the first irreversible pressure induced solid state structural transformation reported for a transition-metal complex.

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0022-4936

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1973 Royal Society of Chemistry, All rights reserved.


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