Title

Changes at the Iodine Nucleus in 1-iodopropane when One Hydrogen at the Carbon-3 Position Is Replaced by Fluorine

Abstract

Pure rotational spectra pertaining to 1-fluoro-3-iodopropane have been recorded using a Search Accelerated Correct Intensity Fourier Transform Microwave Spectrometer. Two conformers were observed and a total of 148 transitions recorded between 8 and 12 GHz. the complete iodine quadrupole coupling tensor has been determined for both observed conformers of 1-fluoro-3-iodopropane and are compared to those values for 1-iodopropane. Quantum chemical calculations were performed on the title molecule which greatly facilitated the spectral assignments and analyses.

Department(s)

Chemistry

International Standard Serial Number (ISSN)

92614

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2009 Elsevier, All rights reserved.


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