The Thermodynamics of Solvation of Methane, Propane, and N-Hexane in the Water-Sulfuric Acid System

Author

Alexander I. Lutsyk
Elisey S. Rudakov
Vadym Mochalin, Missouri University of Science and TechnologyFollow
G. G. Gundilovich

Abstract

The solubilities of methane, propane, and n-hexane in the water-sulfuric acid system measured at 283-343 K were used to calculate the thermodynamic functions of solvation at 298 K. An unusual compensation dependence between ΔW°_s and ΔS°_s, represented by two separate lines corresponding to low and high H₂SO₄ concentrations, was observed.

Recommended Citation

A. I. Lutsyk et al., "The Thermodynamics of Solvation of Methane, Propane, and N-Hexane in the Water-Sulfuric Acid System," Russian Journal of Physical Chemistry A, Focus on Chemistry, vol. 73, no. 3, pp. 386 - 389, Maik Nauka-Interperiodica Publishing, Jan 1999.

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0036-0244

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1999 Maik Nauka-Interperiodica Publishing, All rights reserved.

Publication Date

01 Jan 1999