Title

Concerning the Electron Density at the Pb Nucleus in PbO as a Function of Bond Length

Abstract

High resolution measurements on the J=1←0 transitions of PbO have been performed using a Fourier transform microwave spectrometer. the available transition frequency for the 208Pb18O isotopomer has allowed the rotational molecular field shift parameter for lead, VPb01, in PbO to be determined for the first time. the parameter gives unique insight concerning how the electron density at the Pb nucleus alters as a function of the Pb-O internuclear separation.

Department(s)

Chemistry

International Standard Serial Number (ISSN)

92614

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2007 Elsevier, All rights reserved.


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