A Three-Dimensional Iron(III) Phosphate, [C₂N₂H₁₀]₂[Fe₅F₄(PO₄)(HPO₄)₆]

Author

Amitava Choudhury, Missouri University of Science and TechnologyFollow
Srinivasan R. Natarajan

Abstract

A new iron phosphate, [C₂N₂H₁₀]₂[Fe₅F₄(PO₄)(HPO₄)₆], containing F- ions as part of the framework, has been synthesized hydrothermally using iron acetylacetonate as the source for iron and ethylenediamine (en) as the amine. a network of [Fe(O/F)₆] octahedra and PO₄ tetrahedra, linked through their vertices, forms the three-dimensional architecture with one-dimensional channels bound by 8-T atom (T=Fe, P), wherein the disordered en molecules are located. the connectivity between the Fe centers via Fe-O/F-Fe linkage giving rise to a pentamer unit is worthy of note. Crystal data: tetragonal, space group =P4₃2₁2, a=9.864(1), c=30.353(1) Å, V=2953.1(1) ų, Z=4, R₁=0.025, w. R. _{2 < /sub>=0066.}

Recommended Citation

A. Choudhury and S. R. Natarajan, "A Three-Dimensional Iron(III) Phosphate, [C₂N₂H₁₀]₂[Fe₅F₄(PO₄)(HPO₄)₆]," Journal of Solid State Chemistry, vol. 154, no. 2, pp. 507 - 513, Elsevier, Nov 2000.

The definitive version is available at https://doi.org/10.1006/jssc.2000.8871

Department(s)

Chemistry

Keywords and Phrases

acetylacetone; ethylenediamine; ferric phosphate, article; chemical bond; crystal structure; proton transport; synthesis; temperature dependence

International Standard Serial Number (ISSN)

0022-4596

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2000 Elsevier, All rights reserved.

Publication Date

01 Nov 2000