NMR Studies of a Series of Phenyl Substituted Ferric N-ethyl-N- Phenyldithiocarbamates

Author

Raymund M. Golding
B. D. Lukeman
Ekkehard Sinn, Missouri University of Science and TechnologyFollow

Abstract

The proton NMR results of a series of phenyl substituted tris(N-ethyl-N-phenyldithiocarbamato)-iron(III) complexes have been successfully interpreted assuming the iron atom is in an intermediate crystal field of octahedral symmetry. The substituent in the phenyl ring has very little effect on the energy separation of the 6A 1 and 2T 2 electronic states. However, the substituent substantially influences the mthylene proton isotropic hyperfine interaction constants in the 6A 1 state. These results have been interpreted as arising from changes in the π character of the N-phenyl bond due to the degree of hindered rotation with the aromatic substitution.

Recommended Citation

R. M. Golding et al., "NMR Studies of a Series of Phenyl Substituted Ferric N-ethyl-N- Phenyldithiocarbamates," Journal of Chemical Physics, American Institute of Physics (AIP), Jan 1972.

The definitive version is available at https://doi.org/10.1063/1.1677825

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0021-9606

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1972 American Institute of Physics (AIP), All rights reserved.

Publication Date

01 Jan 1972