Title

An Organically Templated Cobalt Germanate

Abstract

An open-framework cobalt germanate of the formula, [Co2(NH2(CH2)2NH2) 3][Ge9O18(OH)4] has been prepared under solvo/hydrothermal conditions in the presence of ethylenediamine. The germanate is constructed by Ge9O18 clusters and contains eight- and ten-membered channels. Besides connecting two Co sites, the amine also acts as a. bis-chelating agent and protrudes into the eight-membered channel.

Department(s)

Chemistry

Keywords and Phrases

chelating agent; cobalt complex; cobalt derivative; ethylenediamine; germanium derivative, article; chelation; chemical bond; chemical structure; crystal structure; structure analysis; X ray powder diffraction

International Standard Serial Number (ISSN)

0022-4596

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2003 Elsevier, All rights reserved.


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