Title

Octahedral Nickel(II) Dithiocarboxylates

Abstract

Two nickel(II) complexes, NiL2Cl2 and NiL2- (NO3)2·0.3EtOH, with the ligand 1,3-dimethyl- imidazoliumdithiocarboxyalato (L) have been synthesized and characterized by infrared and electronic spectroscopy and magnetic susceptibilities. The complexes exhibit the normal paramagnetism characteristic of octahedral nickel(II). The magnetic moments decrease with falling temperature, indicative of antiferromagnetic coupling, which is greater for the chloride than for the nitrate adduct. Columnar structures with chloro and nitrato bridging are proposed. © 1986.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1986 Elsevier, All rights reserved.


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