Convenient Preparation of [CuX(PCy₃)₂](X = Br, I, SCN, N₃) Complexes

Alternative Title

X-ray crystal structure of [Cu(N₃)(PCy₃)₂] (Cy = cyclo-C6H11)

Author

J. Green
Ekkehard Sinn, Missouri University of Science and TechnologyFollow
Simon Woodward

Abstract

The labile cations [Cu(F-BF3)(PCy3)2] and [Cu(OTf)(PCy3)2] are versatile precursors for the formation of [Cu(X)(PCy3)2] (X = Br, I, SCN, N3) complexes by metathesis with NaX. The azide [Cu(N3)(PCy3)2] is triclinic, space group P1, a = 9.755(4), b = 22.78(1), c = 9.284(6) A ̊, α = 96.76(3), β = 115.36(3), γ = 94.20(5)°, Z = 2. © 1995.

Recommended Citation

J. Green et al., "Convenient Preparation of [CuX(PCy₃)₂](X = Br, I, SCN, N₃) Complexes," Inorganica Chimica Acta, Elsevier, Jan 1995.

The definitive version is available at https://doi.org/10.1016/0020-1693(94)04296-8

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0020-1693

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1995 Elsevier, All rights reserved.

Publication Date

01 Jan 1995