Three-dimensional Organically Templated Open-framework Transition Metal Selenites
One dimensional channels are formed in the three-dimensional open-framework iron selenite [C4N2H12]0.5[Fe2F3(SeO3)2] (I), which was synthesized hydrothermally from FeCl3⋅6 H2O, HF, and SeO2 in the presence of the organic amine piperazine. the same inorganic framework was also obtained with the amines diethylenetetramine, 1,3-diaminopropane, and ethylenediamine. Compound I displays unusual magnetic frustration behavior that is attributed to the tetrahedral geometry.
A. Choudhury et al., "Three-dimensional Organically Templated Open-framework Transition Metal Selenites," Angewandte Chemie International Edition, Wiley-VCH Verlag, Jan 2002.
The definitive version is available at http://dx.doi.org/10.1002/1521-3773(20020104)41:1<158
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