Three-Dimensional Organically Templated Open-Framework Transition Metal Selenites
One dimensional channels are formed in the three-dimensional open-framework iron selenite [C4N2H12]0.5[Fe2F 3(SeO3)2] (I), which was synthesized hydrothermally from FeCl3 · 6H2O, HF, and SeO2 in the presence of the organic amine piperazine. The same inorganic framework was also obtained with the amines diethlenetetramine, 1,3-diaminopropane, and ethylenediamine. Compound I displays unusual magnetic frustration behavior that is attributed to the tetrahedral geometry.
A. Choudhury et al., "Three-Dimensional Organically Templated Open-Framework Transition Metal Selenites," Angewandte Chemie International Edition, vol. 41, no. 1, pp. 158-161, Wiley-VCH Verlag, Jan 2002.
The definitive version is available at https://doi.org/10.1002/1521-3773(20020104)41:1<158::AID-ANIE158>3.0.CO;2-%23
Keywords and Phrases
Amines; Geometry; Magnetic Properties; Magnetic Frustration; Iron Alloys; Iron Derivative; Selenite; Article; Energy; Geometry; Magnetism; Molecular Interaction; Molecular Stability; Synthesis; Temperature Dependence; Thermal Analysis; X Ray Crystallography; Crystals Growth; Iron; Magnetic Properties; Mesoporous Material; Selenium
International Standard Serial Number (ISSN)
Article - Journal
© 2002 Wiley-VCH Verlag, All rights reserved.