Title

Three-dimensional Organically Templated Open-framework Transition Metal Selenites

Abstract

One dimensional channels are formed in the three-dimensional open-framework iron selenite [C4N2H12]0.5[Fe2F3(SeO3)2] (I), which was synthesized hydrothermally from FeCl3⋅6 H2O, HF, and SeO2 in the presence of the organic amine piperazine. the same inorganic framework was also obtained with the amines diethylenetetramine, 1,3-diaminopropane, and ethylenediamine. Compound I displays unusual magnetic frustration behavior that is attributed to the tetrahedral geometry.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2002 Wiley-VCH Verlag, All rights reserved.


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