Title

Magnetic Ordering in [Co(γ-Ch₃C₅H₄NO)₆](ClO₄)₂ I

Alternative Title

Crystal structure and superexchange pathways

Abstract

The crystal structure of the title compound is reported, where the ligand is γ-methylpyridine N-oxide. The crystal data are: space group P21/c, Z = 2, a = 9.498(2) A ̊, b = 10.761(3) A ̊, c = 20.523(7) A ̊, and β = 92.46(2)°. The structure consists of octahedrally-coordinated [Co(γ-CH3C5H4NO)6]2+ ions in a largely two-dimensional network, together with perchlorate ions which exhibit two-fold positional disorder. Likely superexchange paths are discussed. © 1981.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1981 Elsevier, All rights reserved.


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