An organically templated iron sulfate of the formula [HN(CH2)6NH][FeIII Fe2 IIF6(SO4)2] ·[H3O] possessing the kagomé lattice has been prepared and characterized by single-crystal crystallography and other techniques. This mixed-valent iron compound shows complex magnetic properties including spin-glass behavior and magnetic hysteresis. The low-temperature specific heat data show deviation from the T2 behavior found in two-dimensional frustrated systems. Simple calculations have been carried out to understand the properties of this kagomé compound.
C. N. Rao et al., "Properties of a Mixed-Valent Iron Compound with the Kagomé Lattice," Physical Review B (Condensed Matter), vol. B67, no. 13, pp. 1344251-1344255, American Physical Society (APS), Apr 2003.
The definitive version is available at https://doi.org/10.1103/PhysRevB.67.134425
Keywords and Phrases
ferrous sulfate; iron derivative; analytic method; article; calculation; crystal; crystallography; heat; low temperature; technique
International Standard Serial Number (ISSN)
Article - Journal
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