Title

New Chiral Ligands Incorporating Useful Functionality: Racemic Palladium(II) Dichloride Complexes of Bidentate Ligands Containing Two Non-coordinated Ester Groups and Three Chiral Centres of Known Relative Stereochemistry

Abstract

The cycloaddition of a pyridyl-azomethine to dimethylfumarate produces an approximately equimolar mixture of diastereomeric, C 1-symmetric, N,N-bidentate ligands. The corresponding palladium(II) dichloride complexes are readily separated by fractional crystallisation and contain non-coordinated ester groups, one of which lies above the plane of the palladium centre. ©1999 Elsevier Science S.A. All rights reserved.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1999 Elsevier, All rights reserved.


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