New Chiral Ligands Incorporating Useful Functionality: Racemic Palladium(II) Dichloride Complexes of Bidentate Ligands Containing Two Non-coordinated Ester Groups and Three Chiral Centres of Known Relative Stereochemistry

Author

Timothy S. Billson
Jonathan D. Crane
David R. Foster
C. S. L. Russell
Ekkehard Sinn, Missouri University of Science and TechnologyFollow
Simon J. Teat
Nigel A. Young

Abstract

The cycloaddition of a pyridyl-azomethine to dimethylfumarate produces an approximately equimolar mixture of diastereomeric, C 1-symmetric, N,N-bidentate ligands. The corresponding palladium(II) dichloride complexes are readily separated by fractional crystallisation and contain non-coordinated ester groups, one of which lies above the plane of the palladium centre. ©1999 Elsevier Science S.A. All rights reserved.

Recommended Citation

T. S. Billson et al., "New Chiral Ligands Incorporating Useful Functionality: Racemic Palladium(II) Dichloride Complexes of Bidentate Ligands Containing Two Non-coordinated Ester Groups and Three Chiral Centres of Known Relative Stereochemistry," Inorganic Chemistry Communications, Elsevier, Jan 1999.

The definitive version is available at https://doi.org/10.1016/S1387-7003(99)00125-2

Department(s)

Chemistry

International Standard Serial Number (ISSN)

1387-7003

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1999 Elsevier, All rights reserved.

Publication Date

01 Jan 1999