Title

X-ray Absorption Fine Structure Study of the Bound State Electronic Transitions at the Vanadium K and L Edges in Low Symmetry, Molecular, Vanadium-(IV) and -(V) Complexes with Oxyoxime and Oxyoximate Ligands

Abstract

A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of V V in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V-N-O-V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η 2-N-O groups.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1998 Royal Society of Chemistry, All rights reserved.


Share

 
COinS