Ru(II) Tris(3,8-Dibromo-1,10-phenanthroline)—A New Versatile Core for the Divergent Synthesis of Hyperbranched Systems
We report the first synthesis of Ru(II) tris(3,8-dibromo-1,10-phenanthroline) bishexafluorophosphate (1), and we demonstrate its utility as a building core for the divergent synthesis of hyperbranched systems by coupling with phenylacetylene in the preparation of Ru(II) tris(3,8-diphenylethynyl-1,10-phenanthroline) dihexafluorophosphate (2).
L. Sotiriou-Leventis et al., "Ru(II) Tris(3,8-Dibromo-1,10-phenanthroline)—A New Versatile Core for the Divergent Synthesis of Hyperbranched Systems," Synthetic Communications, Taylor & Francis, Jan 2005.
The definitive version is available at https://doi.org/10.1081/SCC-200030975
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