Title

Oxo Methyls of Molybdenum(V), Tungsten(V) and Rhenium(V): X-ray Crystal Structure of (Me₄WO)₂Mg(thf)₄

Abstract

The interaction of MgMe2 or MeLi with MOCl4 (M = W or Mo) leads to the paramagnetic (d1) complexes (Me4MO)2Mg(thf)4 and (Me4MO)Li(thf)2, respectively. The structure of (Me4WO)2Mg(thf)4 has been determined by X-ray crystallography and shown to consist of Mg2+ co-ordinated by thf and square pyramidal Me4WO- units. The preparation of the diamagnetic rhenium(V) compound (Me4ReO)Li(thf)2 is also reported. © 1987.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1987 Elsevier, All rights reserved.


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