Title

Oxygenation of Hydrocarbons Mediated by Mixed-valent Basic Iron Trifluoroacetate and Valence-separated Component Species under Gif-type Conditions Involves Carbon- and Oxygen-centered Radicals

Abstract

Hydrogen-atom abstraction by hydroxyl radicals takes place to generate both tert- and sec-adamantyl radicals in Gif-type oxygenation of adamantane by H2O2 in pyridine/trifluoroacetic acid when the reaction is mediated by [Fe(O2CCF3)2(py)4] or [Fe2O(O2CCF3)4(py)6], which are formed by dissociation of [Fe3O(O2CCF3)6- (L)3] in pyridine (L = H2O, DMSO; see scheme).

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2000 Wiley-VCH Verlag, All rights reserved.


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