Title

Thermochemical Isotope Effects. Chloroform/Chloroform-d and Acetone/acetone-d6 in Selected Solvents

Abstract

Isotope effects on the heats of solution of the isotopic pairs chloroform/chloroform-d and acetone/ acetone-d6 have been measured in a variety of solvents at 25°. While both positive and negative isotope effects have been observed for the heats of solution of these solutes, the transfer of the deuterated compound from cyclohexane (at infinite dilution) to other solvents is in every case more exothermic than the transfer of the parent compound.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1974 American Chemical Society (ACS), All rights reserved.


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