Monomeric, Two-coordinate, Univalent Chromium(I) Compounds: Steric Prevention of Metal-metal Bond Formation

Abstract

Monomeric, two-coordinate, univalent, aryl chromium(I) species [(3,5-iPr2-Ar*)Cr(L)] (L = THF, PMe3) have been synthesized with use of a very bulky terphenyl ligand which prevents Cr-Cr bond formation.

Department(s)

Chemistry

Sponsor(s)

Alexander von Humboldt Foundation. Feodor-Lynen-Fellowship
Petroleum Research Fund
National Science Foundation (U.S.)

International Standard Serial Number (ISSN)

0002-7863

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2007 American Chemical Society (ACS), All rights reserved.

Publication Date

01 Jan 2007

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