Title

A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin Frustration and Long-Range Magnetic Ordering

Abstract

Star formation: Polymeric [Fe33-O)(µ-OAc)6(H2O)3][Fe33-O)µ-OAc)7.52·7H2O is synthesized by linking triangular {Fe33-O)} clusters through anti-anti bridging acetate ligands. Spin frustration and long-range magnetic order coexist in this compound below 4.5 K

Department(s)

Chemistry

Sponsor(s)

National Fund for Scientific Research, Belgium
National Science Foundation (U.S.)
Guangdong Province (China). Science and Technology Department

Keywords and Phrases

Acetate Ligands; Spin Frustration; Antiferromagnetic Materials; Magnetic Properties; Magnetization; Materials Science; Mössbauer Spectroscopy; Spin Dynamics; Iron Compounds; Ferric Acetate; Ferric Ion; Polymer; Unclassified Drug; Chemical Structure; Chemistry; Magnetism; Mössbauer Spectroscopy; Ferric Compounds; Magnetics; Molecular Structure; Polymers; Spectroscopy; Mössbauer

International Standard Serial Number (ISSN)

14337851

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2007 John Wiley & Sons, All rights reserved.


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