Title

Morphology and Rheological Properties of Poly (Butylene Adipate-Co-Terephthalate) and Poly (Lactic Acid)/Clay Composites

Abstract

This work studied Poly(butylene adipateco-terephthalate) (PBAT) and polylactide (PLA) bends compounded with organically modified silicate layers. PBAT is a biodegradable polymer with high ultimate elongation but low modulus. Compounds of 80%PBAT, 20%PLA and 3% organically modified silicate layers showed significantly improved modulus and enhanced thermomechanical performance compared to PBAT. Rheological analyses showed solid-like behavior for the melt, indicating formation of a network structure by the particles in the blend although the clay platelets were partially dispersed in PBAT matrix and a large portion of the platelets was located at the interface based on the electron microscopy analysis. It also showed that the addition of organoclay reduced the dispersed phase domain (i.e., PLA) size significantly.

Meeting Name

69th Annual Technical Conference of the Society of Plastics Engineers

Department(s)

Chemical and Biochemical Engineering

Keywords and Phrases

Clay Platelets; Dispersed Phase; Electron Microscopy Analysis; Low Modulus; Matrix; Network Structures; Organically Modified Silicates; Poly(Lactic Acid); Polylactides; Rheological Analysis; Rheological Property; Thermo-mechanical Performance; Ultimate Elongation

Document Type

Article - Conference proceedings

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2011 Society of Plastics Engineers, All rights reserved.

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